Heterocyclic substituted methanides as promising alternatives to the ubiquitous nacnac ligand

Heterocyclic substituted methanides as promising alternatives to the ubiquitous nacnac ligand.

A series of group 13 complexes containing deprotonated bisheterocyclomethanes have been prepared and structurally as well as spectroscopically characterised. In the case of the parent neutral homo-disubstituted bisheterocyclomethanes bis-(benzoxazol-2-yl)-methane (abbreviated as (NCOC6H4)2CH2) (1) and bis-(benzothiazol-2-yl)-methane (abbreviated as (NCSC6H4)2CH2) (2), two interesting ligand sys...

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Heterocyclic substituted methanides as promising alternatives to the ubiquitous nacnac ligand

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